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Παρασκευή 21 Ιουλίου 2017

Regioselective 1,4-Hydroboration of Pyridines Catalyzed by an Acid-Initiated Boronium Cation

Chem. Commun., 2017, Accepted Manuscript
DOI: 10.1039/C7CC04988A, Communication
Evan Keyzer, Sky Kang, Schirin Hanf, Dominic S Wright
The reaction of the commercially available ammonium salt NH4BPh4 with a pyridine-activated pinacolborane species generates a boronium cation that facilitates the 1,4-selective hydroboration of pyridines in polar solvents. This catalytic...
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